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RSS FeedsMolbank, Vol. 2018, Article M1028: [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-?S]-(tri-4-tolylphosphine-?P)gold(I) (Molbank)

 
 

10 november 2018 12:01:37

 
Molbank, Vol. 2018, Article M1028: [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-?S]-(tri-4-tolylphosphine-?P)gold(I) (Molbank)
 




The synthesis, spectroscopic characterization and X-ray crystal structure of the title compound, (4-tolyl)3PAu[SC(O-i-Pr)=NC6H4NO2-4] (1) are described. Spectroscopy exhibited the expected features confirming the formation of the compound. The molecular structure of 1 confirms the expected linear P–Au–S coordination geometry defined by thiolate-S and phosphane-P atoms. The nearly 7° deviation from linearity is ascribed to the close approach of the imine-bound phenyl group, indicative of a semi-localized Au…π(arene) interaction. The three-dimensional molecular packing is consolidated by methyl- and tolyl-C–H…O(nitro) and tolyl-C–H…π(tolyl) interactions.


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29 viewsCategory: Biochemistry, Chemistry, Molecular Biology
 
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