MyJournals Home  

RSS FeedsDegenerative xanthate transfer to olefins under visible-light photocatalysis (Beilstein Journal of Organic Chemistry)

 
 

14 december 2018 02:00:04

 
Degenerative xanthate transfer to olefins under visible-light photocatalysis (Beilstein Journal of Organic Chemistry)
 


Abstract The degenerative transfer of xanthates to olefins is enabled by the iridium-based photocatalyst [Ir{dF(CF3)ppy}2(dtbbpy)](PF6) under blue LED light irradiation. Detailed mechanistic investigations through kinetics and photophysical studies revealed that the process operates under a radical chain mechanism, which is initiated through triplet-sensitization of xanthates by the long-lived triplet state of the iridium-based photocatalyst. Beilstein J. Org. Chem. 2018, 14, 3047–3058. doi:10.3762/bjoc.14.283


 
91 viewsCategory: Chemistry
 
A tutorial review of stereoretentive olefin metathesis based on ruthenium dithiolate catalysts (Beilstein Journal of Organic Chemistry)
6’-Fluoro[4.3.0]bicyclo nucleic acid: synthesis, biophysical properties and molecular dynamics simulations (Beilstein Journal of Organic Chemistry)
 
 
blog comments powered by Disqus


MyJournals.org
The latest issues of all your favorite science journals on one page

Username:
Password:

Register | Retrieve

Search:

Chemistry


Copyright © 2008 - 2024 Indigonet Services B.V.. Contact: Tim Hulsen. Read here our privacy notice.
Other websites of Indigonet Services B.V.: Nieuws Vacatures News Tweets Nachrichten