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RSS FeedsMolecules, Vol. 24, Pages 288: Microwave-Assisted Dehydrogenative Cross Coupling Reactions in ?-valerolactone with a Reusable Pd/?-cyclodextrin Crosslinked Catalyst (Molecules)

 
 

18 january 2019 14:01:15

 
Molecules, Vol. 24, Pages 288: Microwave-Assisted Dehydrogenative Cross Coupling Reactions in ?-valerolactone with a Reusable Pd/?-cyclodextrin Crosslinked Catalyst (Molecules)
 


Transition-metal mediated C-H bond activation and functionalization is one of the most straightforward and powerful tools in modern organic synthetic chemistry. Oxidative C-H/C-H coupling reactions between two (hetero)arenes under heterogeneous catalysis may be a valuable means for the production of a plethora of bi(hetero)aryls, and one that adheres to the increasing demand for atom-economic and sustainable chemistry. We have therefore developed a reusable heterogeneous catalytic system, which is based on Pd cross-linked ?-cyclodextrin, to perform an efficient microwave-assisted oxidative C-H/C-H cross coupling process between benzothiazoles and methyl thiophene in the presence of green solvents.


 
59 viewsCategory: Biochemistry, Chemistry, Molecular Biology
 
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