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14 january 2021 09:39:55

 
Tuning the solid-state emission of liquid crystalline nitro-cyanostilbene by halogen bonding (Beilstein Journal of Organic Chemistry)
 


Abstract The first example of halogen-bonded fluorescent liquid crystals based on the interaction of iodofluorobenzene derivatives with nitro-cyanostilbenes is reported. The systematic variation of the fluorination degree and pattern indicates the relevance of the halogen bond strength for the induction of liquid crystalline properties. The modular self-assembly approach enables the efficient tuning of the fluorescence behaviour and mesomorphic properties of the assemblies. Beilstein J. Org. Chem. 2021, 17, 124–131. doi:10.3762/bjoc.17.13


 
46 viewsCategory: Chemistry
 
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