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5 march 2021 13:51:01

 
[2 + 1] Cycloaddition reactions of fullerene C60 based on diazo compounds (Beilstein Journal of Organic Chemistry)
 


Abstract The most common variant of fullerene core functionalization is the [2 + 1] cycloaddition process. Of these, reactions leading to methanofullerenes are the most promising. They are synthesized in two main reactions: nucleophilic cyclopropanation according to the Bingel method and thermal addition of diazo compounds. This present review summarizes the material on the synthesis of monofunctionalized methanofullerenes – analogues of [60]PCBM – based on various diazo compounds. The main cyclopropanating agents for the synthesis of monosubstituted methanofullerenes, the optimal conditions and the mechanism of the [2 + 1] cycloaddition, as well as the practical application of the target products are analyzed. Beilstein J. Org. Chem. 2021, 17, 630–670. doi:10.3762/bjoc.17.55


 
54 viewsCategory: Chemistry
 
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