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RSS FeedsMolecules, Vol. 27, Pages 5093: High-Temperature Spin Crossover in Iron(II) Complexes with 2,6-Bis(1H-imidazol-2-yl)pyridine (Molecules)

 
 

10 august 2022 15:51:19

 
Molecules, Vol. 27, Pages 5093: High-Temperature Spin Crossover in Iron(II) Complexes with 2,6-Bis(1H-imidazol-2-yl)pyridine (Molecules)
 


Novel iron(II) coordination compounds containing a ligand 2,6-bis(1H-imidazol-2-yl)pyridine (L), having such a composition as [FeL2]SO4·0.5H2O, [FeL2]Br2·H2O, [FeL2](ReO4)2, [FeL2]B10H10∙H2O, [FeL2]B12H12∙1.5H2O had been synthesized and studied using UV-Vis (diffuse reflectance), infrared, extended X-ray absorption fine structure (EXAFS), and Mössbauer spectroscopy methods, as well as X-ray diffraction and static magnetic susceptibility methods. The analysis of the μeff(Т) dependence in the temperature range of 80–600 K have shown that all the obtained complexes exhibit a high-temperature spin crossover 1А1 « 5Т2.


 
95 viewsCategory: Biochemistry, Chemistry, Molecular Biology
 
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