Energies, Vol. 15, Pages 9043: Occurrence and Migration Mechanisms of Methane in Marine Shale Reservoirs (Energies)

The occurrence mechanism of methane is very important as evaluating the gas-bearing properties of marine shale reservoirs, and the evaluation of the development effect of shale gas wells need to focus on the migration mechanism of methane. In this study, LTNA technology and NMR technology were used to analyze the pores and methane of shale. The results show that inorganic pores have better connectivity, larger pore size, and micro–nano cracks between pores compared to organic pores. Most of the pores in shale are micropores and mesopores, which provide most of the specific surface area, but the contribution of macropores to pore volume cannot be ignored. Adsorbed gas volume depends on the pore surface area and gas pressure, while free gas volume depends on pore volume and gas pressure. The pore structure of micropores and mesopores is complex, and the specific surface area is large. The dispersion force between pore surface molecules and methane molecules is firm, which makes the pore wall an ideal enrichment space for adsorbed gas. Macropores have larger pore volumes and can store more free gas. In the process of gas well development, free gas is first discharged from pores under the action of the pressure gradient. As the pore pressure is lower than the critical desorption pressure, adsorbed gas begins to desorb in large quantities. It should be noted that the desorption process of adsorbed gas is slow and persistent, which makes it impossible for gas wells to achieve higher recovery in a shorter production cycle. Therefore, improving the recovery rate of adsorbed gas is the key to future research on shale gas development effects. This study is helpful in clarifying the occurrence and migration mechanism of methane in marine shale reservoirs and guiding the development of gas wells.