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30 november 2022 10:41:52

Synthetic study toward the diterpenoid aberrarone (Beilstein Journal of Organic Chemistry)

Abstract An approach to aberrarone, an antimalarial diterpenoid natural product with tetracyclic skeleton is reported. Key to the stereoselective preparation of the 6-5-5 tricyclic skeleton includes the mediation of Nagata reagent for constructing the C1 all-carbon quaternary centers and gold-catalyzed cyclopentenone synthesis through C–H insertion. Beilstein J. Org. Chem. 2022, 18, 1625–1628. doi:10.3762/bjoc.18.173

43 viewsCategory: Chemistry
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