Entropy, Vol. 19, Pages 241: Axiomatic Characterization of the Quantum Relative Entropy and Free Energy (Entropy)

Building upon work by Matsumoto, we show that the quantum relative entropy with full-rank second argument is determined by four simple axioms: (i) Continuity in the first argument; (ii) the validity of the data-processing inequality; (iii) additivity under tensor products; and (iv) super-additivity. This observation has immediate implications for quantum thermodynamics, which we discuss. Specifically, we demonstrate that, under reasonable restrictions, the free energy is singled out as a measure of athermality. In particular, we consider an extended class of Gibbs-preserving maps as free operations in a resource-theoretic framework, in which a catalyst is allowed to build up correlations with the system at hand. The free energy is the only extensive and continuous function that is monotonic under such free operations.