Chemistry
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20 july 2017 14:33:53 |
| A new member of the fusaricidin family – structure elucidation and synthesis of fusaricidin E (Beilstein Journal of Organic Chemistry) |
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Tweet Abstract
Two hitherto unknown fusaricidins were obtained from fermentation broths of three Paenibacillus strains. After structure elucidation based on tandem mass spectrometry and NMR spectroscopy, fusaricidin E was synthesized to confirm the structure and the suggested stereochemistry. The synthesis was based on a new strategy which includes an efficient access to the 15-guanidino-3-hydroxypentadecanoyl (GHPD) side chain from erucamide.
Beilstein J. Org. Chem. 2017, 13, 1430–1438. doi:10.3762/bjoc.13.140 |
| 105 viewsCategory: Chemistry |
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