Block copolymers from ionic liquids for the preparation of thin carbonaceous shells (Beilstein Journal of Organic Chemistry)

Abstract This paper describes the controlled radical polymerization of an ionic-liquid monomer by RAFT polymerization. This allows the control over the molecular weight of ionic liquid blocks in the range of 8000 and 22000 and of the block-copolymer synthesis. In this work we focus on block copolymers with an anchor block. They can be used to control the formation of TiO2 nanoparticles, which are functionalized thereafter with a block of ionic-liquid polymer. Pyrolysis of these polymer functionalized inorganic nanoparticles leads to TiO2 nanoparticles coated with a thin carbonaceous shell. Such materials may, e.g., be interesting as battery materials. Beilstein J. Org. Chem. 2017, 13, 1693–1701. doi:10.3762/bjoc.13.163