Chemistry
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21 november 2017 10:36:08 |
| Diastereoselective Mannich reactions of pseudo-C2-symmetric glutarimide with activated imines (Beilstein Journal of Organic Chemistry) |
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Tweet Abstract
As an extension of the boron enolate-based aldol reactions, the oxazolidinone-installed bisimide 1a from 3-(trifluoromethyl)glutaric acid was employed for Mannich reactions with tosylated imines 2 as electrophiles to successfully obtain the corresponding adducts in a stereoselective manner.
Beilstein J. Org. Chem. 2017, 13, 2473–2477. doi:10.3762/bjoc.13.244 |
| 98 viewsCategory: Chemistry |
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