MyJournals Home  

RSS FeedsSynthesis and anion binding properties of phthalimide-containing corona[6]arenes (Beilstein Journal of Organic Chemistry)

 
 

21 august 2019 10:00:28

 
Synthesis and anion binding properties of phthalimide-containing corona[6]arenes (Beilstein Journal of Organic Chemistry)
 




Abstract Functionalized O6-corona[3]arene[3]tetrazines were synthesized efficiently and conveniently by means of a macrocyclic condensation reaction between N-functionalized 3,6-dihydroxyphthalimides and 3,6-dichlorotetrazine under mild conditions in a one-pot reaction manner. The novel macrocycles exist as a mixture of rapidly interconvertible conformers in solution while in the solid state they adopt the conformation in which three phthalimide units are cis,trans-orientated. Acting as electron-deficient macrocyclic hosts, the synthesized O6-corona[3]arene[3]tetrazines self-regulated conformational structures to complex anions in the gas phase and in the solid state owing to the anion–π noncovalent interactions between anions and the tetrazine rings. Beilstein J. Org. Chem. 2019, 15, 1976–1983. doi:10.3762/bjoc.15.193


Del.icio.us Digg Facebook Google StumbleUpon Twitter
 
51 viewsCategory: Chemistry
 
[ASAP] Feasibility of Varied Polyethylene Terephthalate Wastes as a Linker Source in Metal-Organic Framework UiO-66(Zr) Synthesis (Industrial & Engineering Chemistry Research)
[ASAP] Total Synthesis of the Diterpenoid Alkaloid Arcutinidine Using a Strategy Inspired by Chemical Network Analysis (Journal of the American Chemical Society)
 
 
blog comments powered by Disqus


MyJournals.org
The latest issues of all your favorite science journals on one page

Username:
Password:

Register | Retrieve

Search:

Chemistry

Use these buttons to bookmark us:
Del.icio.us Digg Facebook Google StumbleUpon Twitter


Valid HTML 4.01 Transitional
Copyright © 2008 - 2019 Indigonet Services B.V.. Contact: Tim Hulsen. Read here our privacy notice.
Other websites of Indigonet Services B.V.: Nieuws Vacatures News Tweets Travel Photos Nachrichten Indigonet Finances Leer Mandarijn