Chemistry
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17 september 2019 18:03:02 |
| Harnessing enzyme plasticity for the synthesis of oxygenated sesquiterpenoids (Beilstein Journal of Organic Chemistry) |
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Tweet Abstract
8-Methoxy-γ-humulene, (E)-8-methoxy-β-farnesene, 12-methoxy-β-sesquiphellandrene and 12-methoxyzingiberene can be synthesised in amorphadiene synthase-catalysed reactions from 8- and 12-methoxyfarnesyl diphosphates due to the highly plastic yet tightly controlled carbocationic chemistry of this sesquiterpene cyclase.
Beilstein J. Org. Chem. 2019, 15, 2184–2190. doi:10.3762/bjoc.15.215 |
| 170 viewsCategory: Chemistry |
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