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1 december 2020 15:17:10

 
Controlled decomposition of SF6 by electrochemical reduction (Beilstein Journal of Organic Chemistry)
 


Abstract The electroreduction of SF6 is shown at ambient temperature in acetonitrile using an array of platinum microelectrodes to improve the electrical detection. Its half reduction potential occurs at −2.17 V vs Fc+/Fc. The exact number of electrons for the full consumption of sulfur hexafluoride was determined and this gas further quantitatively transformed into environmentally benign fluoride anion and sulfur by electrochemical reduction. Beilstein J. Org. Chem. 2020, 16, 2948–2953. doi:10.3762/bjoc.16.244


 
53 viewsCategory: Chemistry
 
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