Chemistry
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16 september 2021 15:59:47 |
| Enantioselective PCCP Brønsted acid-catalyzed aminalization of aldehydes (Beilstein Journal of Organic Chemistry) |
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Tweet Abstract
Here we present an enantioselective aminalization of aldehydes catalyzed by Brønsted acids based on pentacarboxycyclopentadienes (PCCPs). The cyclization reaction using readily available anthranilamides as building blocks provides access to valuable 2,3-dihydroquinazolinones containing one stereogenic carbon center with good enantioselectivity (ee up to 80%) and excellent yields (up to 97%).
Beilstein J. Org. Chem. 2021, 17, 2433–2440. doi:10.3762/bjoc.17.160 |
| 166 viewsCategory: Chemistry |
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